⚗️ Chemistry — Chapter 8

Reaction Types & Predicting Products

Master the five reaction types, learn when to use the activity series and solubility chart, and predict products like a pro.

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Test Review — Section by Section

This follows the exact numbering on your study guide sheet. Find the section → find the answer.

1. Chemical Reactions

• List the five changes that are evidence a chemical reaction has occurred

  • Color change — the substance changes color (e.g., iron rusting turns orange)
  • Gas production — bubbles or fizzing appear (e.g., baking soda + vinegar)
  • Precipitate forms — a solid appears in a liquid mixture
  • Temperature change — the mixture gets noticeably hotter or colder
  • Light or energy released — glowing, sparking, or flame

• What is the difference between reactants and products?

Reactants are the starting substances — they go on the left side of the arrow.
Products are the new substances that are formed — they go on the right side of the arrow.

Reactants → Products

• Know the symbols that indicate states of matter

(s)
Solid
(l)
Liquid
(g)
Gas
(aq)
Aqueous
(dissolved in water)

These are written after each formula in an equation, like: NaCl(aq) + AgNO₃(aq) → AgCl(s) + NaNO₃(aq)

2. Balancing Equations

• What is the law of conservation of mass?

Matter cannot be created or destroyed in a chemical reaction. The total mass of the reactants must equal the total mass of the products. This means every atom that goes in must come out — which is why we balance equations.

• What is the difference between a coefficient and a subscript? Which do you add to balance?

Coefficient = the big number in front of a formula. It multiplies the entire molecule. ✅ You change THIS to balance.

Subscript = the small number inside the formula. It tells how many of that atom are in one molecule. 🚫 NEVER change this — it changes the substance itself.

Example: In 2HO, the 2 is the coefficient (2 molecules) and the is the subscript (2 hydrogen per molecule). Total hydrogen = 2 × 2 = 4.

• List the rules for balancing equations

  • Never change subscripts — only add or change coefficients
  • Balance metals first, then non-metals, then oxygen, then hydrogen last
  • Start with the most complex formula — anchor it with a coefficient of 1
  • Use the odd-even trick — if an element is odd on one side and even on the other, double the odd side
  • Keep polyatomic ions together — if SO₄, NO₃, PO₄, etc. appear intact on both sides, count them as one unit
  • Always verify — recount every atom on both sides when done
  • Reduce to lowest ratio — coefficients should be the smallest whole numbers possible

• Balance the following:

These are the specific equations from your study guide:

a. Mg + Zn(NO₃)₂ → Mg(NO₃)₂ + Zn

Already balanced! Mg=1, Zn=1, NO₃=2 on each side.

b. Fe(OH)₃ + H₃PO₄ → FePO₄ + H₂O

Fe(OH)₃ + H₃PO₄ → FePO₄ + 3H₂O

Fe=1=1 ✓, PO₄=1=1 ✓, H: 3+3=6 → 3×2=6 ✓, O: 3+4=7... treat PO₄ as unit → O from OH: 3 left, 3 in 3H₂O right ✓

c. SO₂ + H₂O → H₂SO₃

Already balanced! S=1, O=2+1=3, H=2 on each side.

3. Writing Word Equations and Balancing

• Review rules for correctly writing chemical formulas

  • The metal (cation) is always written first, the non-metal (anion) second: NaCl, not ClNa
  • Use Roman numerals for transition metals to show charge: Iron(II) = Fe²⁺ → FeCl₂, Iron(III) = Fe³⁺ → FeCl₃
  • Polyatomic ions with a subscript go in parentheses: Ca(OH)₂, not CaOH₂
  • Use naming prefixes for covalent compounds: mono=1, di=2, tri=3, tetra=4, penta=5

• What is a diatomic element and what are the diatomic elements?

A diatomic element is one that naturally exists as a pair of two atoms bonded together when it's by itself (not in a compound).

"Have No Fear Of Ice Cold Beer" → H₂, N₂, F₂, O₂, I₂, Cl₂, Br₂

When these elements appear alone in an equation, always write them with a ₂ subscript.

• Write the following equations and balance:

a. Aluminum metal reacts with oxygen gas to give aluminum oxide.

Al + O₂ → Al₂O₃ (remember: O₂ is diatomic!)

4Al + 3O₂ → 2Al₂O₃

b. Iron (II) sulfide reacts with hydrochloric acid to form hydrosulfuric acid and iron (II) chloride.

FeS + HCl → H₂S + FeCl₂ (Iron II = Fe²⁺)

FeS + 2HCl → H₂S + FeCl₂

c. Dinitrogen trioxide and water react to form nitrous acid.

N₂O₃ + H₂O → HNO₂ (di=2, tri=3)

N₂O₃ + H₂O → 2HNO₂

4. List the Five Types of Reactions

Full descriptions, patterns, and examples are in the Five Reaction Types section below. Here's the quick summary:

Synthesis
A + B → AB
Decomposition
AB → A + B
Single Replace
A + BC → AC + B
Double Replace
AB + CD → AD + CB
Combustion
CₓHᵧ + O₂ → CO₂ + H₂O

↓ Scroll to the "5 Types" section for full details, examples, decision tree, and a comprehension check quiz.

5. Predicting Products

• Which type of reaction would require you to use your activity series of metals?

Single Replacement — the activity series tells you whether the lone element is reactive enough to replace the element in the compound. Higher on the chart = more reactive = can replace. ↓ See the interactive Activity Series tool below.

• Which type of reaction would require the use of the solubility chart?

Double Replacement — after swapping the cations, the solubility chart tells you if a precipitate (insoluble solid) forms. If it does, the reaction happens. If all products are soluble, no reaction. ↓ See the interactive Solubility Chart below.

• Predict products for the following:

a. magnesium bromide + chlorine →

Single replacement (halogen). Cl₂ is higher than Br₂ in the halogen series → reaction happens.

MgBr₂ + Cl₂ → MgCl₂ + Br₂

b. sulfuric acid + sodium hydroxide →

Double replacement (acid + base neutralization). Products: sodium sulfate + water.

H₂SO₄ + 2NaOH → Na₂SO₄ + 2H₂O

c. C₂H₆ + O₂ →

Combustion (hydrocarbon + oxygen). Products are always CO₂ + H₂O.

2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O

d. Mg + O₂ →

Synthesis (two elements combining).

2Mg + O₂ → 2MgO

e. HgO →

Decomposition (one compound breaking apart).

2HgO → 2Hg + O₂

• Predict products — Solubility chart problems:

For these, swap the cations, then check the solubility chart. If all products are aqueous (soluble), write "No Reaction."

f. Sodium bromide + silver chlorate →

Swap: NaClO₃ + AgBr. Check solubility: AgBr = Insoluble → precipitate forms!

NaBr + AgClO₃ → NaClO₃ + AgBr↓

Potassium sulfate + calcium acetate →

Swap: K acetate + CaSO₄. Check: K₂(C₂H₃O₂) = Soluble, CaSO₄ = Partially soluble.

K₂SO₄ + Ca(C₂H₃O₂)₂ → 2KC₂H₃O₂ + CaSO₄↓

Lithium hydroxide + strontium nitrate →

Swap: LiNO₃ + Sr(OH)₂. Check: LiNO₃ = Soluble, Sr(OH)₂ = Soluble. All products dissolve → No Reaction.

No Reaction (all products are soluble)

6. More Practice

Your teacher says: "Go back and re-work worksheets we have done in class." Both practice worksheets are below with interactive problems and full solutions — scroll down to Practice 1 and Practice 2.

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The Five Reaction Types

Every chemical reaction falls into one of these five categories. Learn the pattern for each and you can identify any reaction.

1. Synthesis (Combination)

A + B → AB
Two or more substances combine to form one new compound. Think: "building something bigger."
2H₂ + O₂ → 2H₂O
2Mg + O₂ → 2MgO
N₂O₅ + H₂O → 2HNO₃
🔑 Clue: Only ONE product. Multiple reactants combine into a single compound.

2. Decomposition

AB → A + B
One compound breaks apart into two or more simpler substances. The opposite of synthesis.
2HgO → 2Hg + O₂
2NaClO₃ → 2NaCl + 3O₂
ZnCO₃ → ZnO + CO₂
🔑 Clue: Only ONE reactant. It splits into multiple products.

3. Single Replacement

A + BC → AC + B
A lone element kicks out another element from a compound, taking its place. Like cutting in line.
Zn + 2HCl → ZnCl₂ + H₂
2Al + 6HCl → 2AlCl₃ + 3H₂
Cl₂ + 2KBr → 2KCl + Br₂
🔑 Clue: An element + a compound → a different element + a different compound. Use the Activity Series to check if the reaction will happen!

4. Double Replacement

AB + CD → AD + CB
Two compounds swap partners. The positive ion from each compound switches to the other compound.
NaBr + AgNO₃ → NaNO₃ + AgBr↓
Ca(OH)₂ + 2HNO₃ → Ca(NO₃)₂ + 2H₂O
Na₂CO₃ + 2HCl → 2NaCl + H₂O + CO₂
🔑 Clue: Two compounds react, ions trade places. Use the Solubility Chart to check if a precipitate forms!

5. Combustion

CₓHᵧ + O₂ → CO₂ + H₂O
A hydrocarbon (contains C and H) burns in oxygen, always producing carbon dioxide and water.
CH₄ + 2O₂ → CO₂ + 2H₂O
2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O
C₃H₈ + 5O₂ → 3CO₂ + 4H₂O
🔑 Clue: A carbon-hydrogen compound + O₂. Products are ALWAYS CO₂ + H₂O.

🌲 Decision Tree: How to Identify the Reaction Type

✅ Quick Check — Can You Identify the Type?

The Activity Series

This chart tells you one thing: will a single replacement reaction actually happen? A more reactive element can replace a less reactive one — but not the other way around.

📋 When Do I Use This?

ONLY for single replacement reactions (element + compound → new element + new compound). The activity series tells you if the lone element is reactive enough to kick out the element it's trying to replace.

⚡ How to Read It

Elements are ranked from most reactive (top) to least reactive (bottom). The rule is simple:

Example: Fe + CuSO₄ → ? Iron (Fe) is HIGHER than copper (Cu) in the series, so iron CAN replace copper. → FeSO₄ + Cu ✓

Example: Cu + ZnSO₄ → ? Copper (Cu) is LOWER than zinc (Zn), so copper CANNOT replace zinc. → No Reaction ✗

🔍 Interactive Activity Series — Click two elements to compare

Click any element in the metals column to see if it can replace another. Higher = more reactive.

Click a metal to start comparing.
MetalSymbolReactivity

Halogens (separate series)

HalogenSymbol
FluorineF₂
ChlorineCl₂
BromineBr₂
IodineI₂

Halogens have their own order. F₂ is the most reactive halogen and can replace any below it.

🧪
The Solubility Chart

This chart tells you one thing: will a double replacement reaction produce a precipitate (solid)? If at least one product is insoluble, the reaction happens.

📋 When Do I Use This?

ONLY for double replacement reactions (two compounds swap ions). After you write the predicted products, look up each product in this chart. If a product is insoluble (I), it precipitates out → reaction happens. If ALL products are soluble (S) → no reaction.

⚡ How to Read It

Find the cation (positive ion, left column) and the anion (negative ion, top row). The cell where they meet tells you:

Example: Will AgBr form a precipitate? Find Silver (Ag) row, Bromide column → I (insoluble). Yes! AgBr precipitates out ↓

🔍 Interactive Solubility Chart — Click a cell to check

Find the cation (row) and anion (column). The cell tells you if the compound is soluble.

Click any cell in the chart to learn about that compound.
S = Soluble
P = Partially soluble
I = Insoluble
D = Decomposes
= Not common
🎯
Predicting Products — The Master Flowchart

This is where it all comes together. Follow this flowchart for any reaction.

🗺️ The 4-Step Process

Worked Example: Predicting a Single Replacement

Problem: Mg + Zn(NO₃)₂ → ?

1
Identify type
An element (Mg) + a compound (Zn(NO₃)₂). That's a single replacement.
2
Check Activity Series
Is Mg above Zn? Yes! Mg is more reactive → reaction happens.
3
Write products
Mg replaces Zn: Mg + Zn(NO₃)₂ → Mg(NO₃)₂ + Zn
4
Balance
Already balanced! Each side: Mg=1, Zn=1, N=2, O=6. ✓
Answer
Mg + Zn(NO₃)₂ → Mg(NO₃)₂ + Zn — Single Replacement

Worked Example: Predicting a Double Replacement

Problem: NaBr + AgNO₃ → ?

1
Identify type
Two compounds reacting. That's a double replacement.
2
Swap the cations
Na⁺ pairs with NO₃⁻ → NaNO₃. Ag⁺ pairs with Br⁻ → AgBr.
3
Check Solubility Chart
NaNO₃ → Soluble (S). AgBr → Insoluble (I)! Precipitate forms → reaction happens.
4
Write & balance
NaBr + AgNO₃ → NaNO₃ + AgBr↓ Already balanced!
Answer
NaBr + AgNO₃ → NaNO₃ + AgBr↓ — Double Replacement
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Practice Worksheet 1

22 problems: balance equations, write word equations, identify reaction types. Try each one, then click "Show Solution."

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Practice Worksheet 2 — Chapter 8

25 more equations to balance and identify. Every problem is interactive with smart feedback.

Quick Reference Cheat Sheet

Pin this to your brain before the test.

🔬 5 Reaction Types

Synthesis: A + B → AB
Decomposition: AB → A + B
Single Replacement: A + BC → AC + B
Double Replacement: AB + CD → AD + CB
Combustion: CₓHᵧ + O₂ → CO₂ + H₂O

🌲 Quick ID Method

1 reactant → Decomposition
1 product → Synthesis
Element + compound → Single Replace
2 compounds swap → Double Replace
CₓHᵧ + O₂ → Combustion

⚡ Activity Series Rule

Single replacement only!
Higher replaces lower → reaction ✓
Lower can't replace higher → no reaction ✗
Metals and halogens have separate series.

🧪 Solubility Rule

Double replacement only!
Swap the cations, then check the chart.
Product is I → precipitate forms → reaction ✓
All products S → no reaction ✗

🔗 Polyatomic Ions

"OH NO, Stop POuring COffee!"
OH (hydroxide) · NO₃ (nitrate)
SO₄ (sulfate) · PO₄ (phosphate)
CO₃ (carbonate)

🧬 Diatomic Elements

"Have No Fear Of Ice Cold Beer"
H₂ · N₂ · F₂ · O₂ · I₂ · Cl₂ · Br₂
Always pairs when alone!

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Helpful Video Resources

Free videos from top educators.

5 Types of Chemical Reactions
The Organic Chemistry Tutor
🔥 Best Overview
Predicting Products of Chemical Reactions
Tyler DeWitt
Step by Step
Activity Series — How to Use It
Professor Dave Explains
Clear Explanation
Solubility Rules — Easy Memorization
Melissa Maribel
Memorization
Chemical Reactions — Crash Course Chemistry
CrashCourse
Fun & Fast
Balancing Equations — Practice Problems
The Organic Chemistry Tutor
Practice